Are your rims actually rusty on the inside? Mine were pretty clean (original paint, too), so I just washed them and that's it. The tubeless tires use soapy water for mounting. Since we have tubes, I just used the good old tire talc powder. Both on the tube and inside the tire (spread it around with a piece of cloth, etc). Do not use organic baby powder for automotive tires ๐คฃ
You don't have to worry about setting the bead, etc. Your biggest concern should be how to not pinch the tube in between the tire and the rim. Also, make sure that you have the correct-size tubes. One of my old tubes had a fold in it. When I put the tires on, I inflated them to around 10 psi, just to hold shape, and then pushed around the sidewall, on both sides, to make sure that the tube was nicely seated in the middle of the rim.